[1]陈宇飞,郭红缘,楚洪月,等.OMMT/PES/BMI复合材料的微观形貌与性能[J].哈尔滨理工大学学报,2019,(02):103-108.[doi:10.15938/j.jhust.2019.02.015]
 CHEN Yu fei,GUO Hong yuan,et al. Micromorphology and Properties of OMMT/PES/BMI Composites[J].哈尔滨理工大学学报,2019,(02):103-108.[doi:10.15938/j.jhust.2019.02.015]
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OMMT/PES/BMI复合材料的微观形貌与性能()
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《哈尔滨理工大学学报》[ISSN:1007-2683/CN:23-1404/N]

卷:
期数:
2019年02期
页码:
103-108
栏目:
材料科学与工程
出版日期:
2019-04-25

文章信息/Info

Title:
 Micromorphology and Properties of OMMT/PES/BMI Composites
文章编号:
1007-2683(2019)02-0103-06
作者:
 陈宇飞12郭红缘2楚洪月2汪波涛2马英一2滕成君3
 (1哈尔滨理工大学 工程电介质及应用技术教育部重点实验室,黑龙江 哈尔滨 150080;
2哈尔滨理工大学 材料科学与工程学院,黑龙江 哈尔滨 150040;
3哈尔滨市香坊区疾病预防控制中心,黑龙江 哈尔滨 150030)
Author(s):
 CHEN Yufei1 2GUO Hongyuan2CHU Hongyue2WANG Botao2MA Yingyi2TENG Chengjun3
 (1Harbin University of Science and Technology, Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin 150080, China;
2School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150040, China;
3Harbin Xiangfang District Center for Disease Control and Prevention, Harbin 150030, China)
关键词:
 双马来酰亚胺树脂有机蒙脱土聚醚砜力学性能热学性能
Keywords:
 Bismaleimide organic montmorillonite polyethersulfone mechanical properties thermal properties
分类号:
TB332
DOI:
10.15938/j.jhust.2019.02.015
文献标志码:
A
摘要:
 采用烯丙基化合物和聚醚砜(PES)增韧双马来酰亚胺(BMI),同时掺杂有机化蒙脱土(OMMT),制备OMMT/PES/BMI多相复合材料,研究并分析了复合材料的微观形貌和力学性能、热学性能及微观与性能的关系。SEM测试结果表明:OMMT含量适当时,PES和OMMT在基体中分散均匀,两相间的界面不清晰且粘结紧密,有效的吸收、转移和消散外界应力,呈现韧性断裂。力学性能测试结果表明:当OMMT时质量分数为3%,材料的弯曲强度和冲击强度达到最大值,为13936MPa和1477kJ/mm2,比基体分别提高了3938 %和5796 %。热重分析表明:PES的加入会略微降低材料的热分解温度,但加入OMMT可以弥补PES所带来的影响并提高材料的耐热性,当OMMT加量质量分数为3%时,其热分解温度为45676℃,较基体提高1768℃。
Abstract:
 Allyl compounds and polyether sulfone(PES) were used to modify bismaleimide Meanwhile, organically montmorillonite(OMMT) was doped to prepare OMMT/PES/BMI multiphase composites The microstructure and mechanical properties, thermal properties and the relationship between them were studied and analyzed SEM test results showed that PES resin and OMMT dispersed uniformly in polymer matrix and the interface between the two phases was not clear and the bond was close, external stress was absorbed, transfered and dissipated effectively, while the content of OMMT was appropriate, so that the composites exhibited ductile fracture Mechanical properties of the composites showed that bending strength and impact strength reached 13936MPa and 1477kJ/mm2, to improve 3938% and 5796% than that of the matrix, respectively, when the content of OMMT is 3% The thermal decomposition temperature (Td) of the composite materials decreased slightly because of PES, but this phenomenon could be remedy by OMMT, Td of composite (3%OMMT/2%PES/BMI) reached 45676℃ and improved 1768℃ than that of the matrix.

参考文献/References:

[1]BABKIN Alexander, ERDNIGORYAEV Erdni M, OLOPCHENKO Alexander V, et al. Mechanical and Thermal Properties of Modified Bismaleimide Matrices Toughened by Polyetherimides and Polyimide[J]. Polymers for Advanced Technologies, 2016, 27(6): 774.
[2]POLGAR Lorenzo Massimo, CERPENTIER Robin R J, VERMEIJ Gijs H, et al. Influence of the Chemical Structure of Crosslinking Agents on Properties of Thermally Reversible NetworksPure and Applied Chemistry, 2016, 88(12): 1103.
[3]MEHTA Brinda, WATT Paula, SOUCEK Mark D, et al. Moderate Temperature Curing of Plant Oils with Bismaleimides via the Ene Reaction[J]. Industrial & Engineering Chemistry Research, 2016, 55(45): 11727.
[4]WU Guanglei, KOU Kaichang, ZHUO Longhai, et al. Preparation and Characterization of Novel Dicyanate/benzoxazine/bismaleimide Copolymer [J]. Thermochimica Acta, 2013, 559: 86.
[5]CAPKOVA P, MATOUSEK J, REJNEK J, et al. Effect of Plasma Treatment on Structure and Surface Properties of Montmorillonite[J]. Applied Clay Science, 2016, 129: 15.
[6]HELLRUP Joel, HOLMBOE Michael, NARTOWSKI Karol P, et al. Structure and Mobility of Lactose in Lactose/Sodium Montmorillonite Nanocomposites[J]. Langmuir, 2016, 32(49): 13214.
[7]申利国. 聚醚砜(PES)膜改性及抗污染性能研究[D]. 上海: 中国科学院大学, 2014: 10.
[8]MARTIN Antonio, ARSUAGA Jesus M, ROLDAN, Nuria, et al. Effect of Amine Functionalization of SBA15 Used as Filler on the Morphology and Permeation Properties of Polyethersulfonedoped Ultrafiltration Membranes[J]. Journal of Membrane Science, 2016, 520: 8.
[9]GB/T1043.1-2008, 塑料-简支梁冲击性能的测定[S]. 北京: 中国标准出版社, 2008.
[10]GB/T 2567-2008, 树脂浇铸体性能试验方法[S]. 北京: 中国标准出版社, 2008.
[11]KALIAVARADHAN Kumudha, MUTHUSAMY Sarojadevi. Synthesis and Characterization of Various Phenylene Diaminebased Bismaleimidecontaining Phthalonitrile Resins[J]. Polymer Bulletin, 2016, 73(7): 1921.
[12]安学锋, 张晨乾. PES颗粒层间增韧碳纤维/双马树脂RTM复合材料[J]. 复合材料学报, 2013, 0(S1): 65.
[13]CAROLAN D, LVANKOVIC A, KINLOCH A J, et al. Toughening of Epoxybased Hybrid Nanocomposites[J]. Polymer, 2016, 97: 179.
[14]KARAKEHYA Naile, BILGIC Ceyda. Inverse Gas Chromatographic Determination of the Surface Energy of PMMA and PMMA/organophilic Montmorillonite Nanocomposites[J]. Surface and Interface Analysis, 2016, 48(7): 519.
[15]王鉴, 臧伟鹏, 祝宝东, 等. 蒙脱土表面改性研究进展[J]. 硅酸盐通报, 2015, 34(3): 749.
[16]GIBSON Ronald F. A Review of Recent Research on Mechanics of Multifunctional Composite Materials and Structures[J]. Composite Structures, 2010, 92(12): 2793.
[17]徐丰, 郭伟国, 付昆昆, 等. 不同应变速率下纳米橡胶颗粒对环氧树脂的增韧特性与机理分析[J]. 高分子学报, 2015, 9: 1092.
[18]GHADAM F, DADFAR M R, KAZAZI M. Hotcured Epoxynanoparticulatefilled Nanocomposites: Fracture Toughness Behavior[J]. Engineering Fracture Mechanics, 2016, 162: 193.
[19]卫凌松. 聚醚砜抗静电防腐涂料的制备及性能研究[D]. 长春: 吉林大学, 2015: 14.
[20]李金梅, 黄晓玲, 苏海全. γ-氨丙基二甲基乙氧基硅烷修饰蒙脱土及硅烷化蒙脱土的性能[J]. 化工进展, 2014, 33(1): 178.
[21]WU Guanglei, CHENG Yonghong, WANG Kuikui, et al. Fabrication and Characterization of OMMT/BMI/CE Composites with Low Dielectric Properties and High Thermal Stability for Electronic Packaging[J]. Journal of Materials ScienceMaterials in Electronics, 2016, 27(6): 5592.

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备注/Memo

备注/Memo:
 收稿日期:2017-03-23
基金项目:国家自然科学基金(21604019);哈尔滨创新人才专项(2015RAXXJ029)
作者简介:郭红缘(1994—),男,硕士研究生
通信作者:
陈宇飞(1963—),女,博士,教授,E-mail:chenyufei@hrbust.edu.cn
更新日期/Last Update: 2019-05-17