[1]张光宇,尹雁,赵鹏飞,等. 平面微型超级电容器石墨烯电极制备与表征[J].哈尔滨理工大学学报,2019,(01):132-137.[doi:10.15938/j.jhust.2019.01.022]
 ZHANG Guang yu,YIN Yan,ZHAO Peng fei,et al. Preparation and Characterization of Graphene Electrode for Planar MicroSupercapacitor[J].哈尔滨理工大学学报,2019,(01):132-137.[doi:10.15938/j.jhust.2019.01.022]
点击复制

 平面微型超级电容器石墨烯电极制备与表征
()
分享到:

《哈尔滨理工大学学报》[ISSN:1007-2683/CN:23-1404/N]

卷:
期数:
2019年01期
页码:
132-137
栏目:
管理科学与工程
出版日期:
2019-02-25

文章信息/Info

Title:
 Preparation and Characterization of Graphene Electrode 
for Planar MicroSupercapacitor

作者:
 张光宇尹雁赵鹏飞刘琳婧李闯
 吕胤霖,陈玉娟,朱大福,杨昕瑞(哈尔滨理工大学 应用科学学院,黑龙江 哈尔滨 150080)
Author(s):
 ZHANG GuangyuYIN YanZHAO PengfeiLIU LinjingLI ChuangL YinlinCHEN YujuanZHU DafuYANG Xinrui
 (School of Applied Sciences, Harbin University of Science and Technology, Harbin 150080, China)
关键词:
 关键词:石墨烯化学气相沉积平面微型超级电容器
Keywords:
 Keywords:graphene chemical vapor deposition planar microsupercapacitor
分类号:
O646
DOI:
10.15938/j.jhust.2019.01.022
文献标志码:
A
摘要:
 摘要:为了研究化学气相沉积法(CVD)制备石墨烯电极性能,通过对CVD工艺参数的改进,成功地制备出了符合全固态平面微型超级电容器离子传输机制所需要的石墨烯薄膜电极。对比相同生长时间,不同甲烷浓度的石墨烯薄膜的性能;对比相同甲烷浓度,不同生长时间的石墨烯薄膜性能。结果表明,温度1000℃、甲烷流量35sccm、氢气流量10sccm、生长时间60min时,制备出的石墨烯薄膜质量和性能最好。此时石墨烯薄膜具有较低的薄膜方阻(6028Ω/sq-15575Ω/sq),厚度为125nm。为平面微型超级电容器的进一步研究提供了重要参考。
Abstract:
 Abstract:Considering the low performance of graphene electrode prepared by chemical vapor deposition (CVD) method, the graphene film electrode required for the ion transport mechanism of the solid planar micro super capacitor was successfully prepared through improved the craft parameter The properties of graphene films with the same growth time and different methane flow rate were compared, and the performances of graphene films with the same methane flow rate and different growth time were compared The results show that the graphene films with the best quality and performance when the growth temperature, methane flow rate, hydrogen flow rate and the growth time were 1000℃, 35sccm, 10sccm and 60min, respectively Moreover, the graphene film has a lower Square resistance of 6028Ω/sq-15575Ω/sq, and the thickness of the film is 125nm This study provides an important reference for the further research of the planar micro capacitor

参考文献/References:

 [1]HU H, PEI Z,Ye C Recent Advances in Designing and Fabrication of Planar Microsupercapacitors for Onchip Energy Storage[J]. Energy Storage Materials, 2015(1):82[2]KURRA N, JIANG Q,ALSHAREEF H N A General Strategy for the Fabrication of High Performance Microsupercapacitors[J]. Nano Energy, 2015(16):1
[3]SUN X Z, ZHANG X, HUANG B, et al Effects of Separator on the Electrochemical Performance of Electrical DoublrLayer Capacitor and Hybrid BatterSupercapacitor[J]. Acta PhysicoChimica, 2014, 30(3):485
[4]LAMBERT S M, Pickert V, Holden J, et al Comparison of Supercapacitor and Lithiumion Capacitor Technologies for Power Electronics Applications[C]// Iet International Conference on Power Electronics, Machines and Drives IET, 2010:1
[5]HUI S Y Planar Wireless Charging Technology for Portable Electronic Products and Qi[J]. Proceedings of the IEEE, 2013, 101(6):1290
[6]KURRA N, HOTA M K, Alshareef H N Conducting Polymer Microsupercapacitors for Flexible Energy Storage and Ac Linefiltering[J]. Nano Energy, 2015(13):500
[7]FRACKWIAK E Carbon Materials for Application[J]. Physical Chemistry Chemical Physics Pccp, 2007, 9(15):1774
[8]XIONG G, MENG C, Reifenberger R G, et al A Review of GrapheneBased Electrochemical Microsupercapacitors[M]. Electroanalysis, 2014,26(1):30
[9]BEIDAGHI M,WANG C MicroSupercapacitors Based on Interdigital Electrodes of Reduced Graphene Oxide and Carbon Nanotube Composites with Ultrahigh Power Handling Performance[J]. Advanced Functional Materials, 2012, 22(21):4500
[10]JOHN R M, Outlaw R A,Holloway B C Graphene DoubleLayer Capacitor with ac LineFiltering Performance[J]. Science, 2010,329(5999):1637
[11]YAN H,LOW T, Guinea F, et al Tunable PhononInduced Transparency in Bilayer Graphene Nanoribbons[J]. Nano Letters, 2013,14(8):4581
[12]LI J, ZHOU Y,QUAN B, et al Graphenemetamaterial Hybridization for Enhanced Terahertz Response[J]. Carbon, 2014,78(18):102
[13]沈宸, 陆云 石墨烯/导电聚合物复合材料在超级电容器电极材料方面的研究进展[J].高分子学报, 2014(10):1328
[14]陈仲欣, 卢红斌 石墨烯-聚苯胺杂化超级电容器电极材料[J]. 高等学校化学学报,2013(9):2020
[15]WU Z S, PARVEZ K, FENG X, et al Graphenebased inplane Microsupercapacitors with High Power and Energy Densities[R]. Nature Communications, 2013, 4(9):2487
[16]Yoo J J, BALAKRISHNAN K, Huang J, et al Ultrathin Planar Graphene Supercapacitors[J]. ACS Publications , 2011,11(4): 1423
[17]CHOUBAK S, LEVESQUE PL,Gaufres E, et al Graphene CVD: Interplay Between Growth and Etching on Morphology and Stacking by Hydrogen and Oxidizing Impurities[J]. Journal of Physical Chemistry C, 2016, 118(37):21532
[18]TIAN J, HU B,WEI Z, et al Surface Structure Deduced Differences of Copper Foil and Film for Graphene CVD Growth[J]. Applied Surface Science, 2014, 300(2):73
[19]CABREROVILATELA A, WEATHERUP R S,BRAEUNINGERWEIMER P, et al Towards a General Growth Model for Graphene CVD on Transition Metal Catalysts[J]. Nanoscale, 2016, 8(4):2149
[20]BHAVIRIPUDI S, JIA X, DRESSELHAUS M S, et al Role of Kinetic Factors in Chemical Vapor Deposition Synthesis of Uniform Large Area Graphene Using Copper Catalyst[J]. Nano Letters, 2010, 10(10): 4128
[21]GAO W,SINGH N, SONG L, et al Diret Laser Writing of Microsupercapacitors on Hydrated Graphite Oxide Films[J]. Nature Nanotechnology, 2011,6(8):496
[22]WANG Y, SHI Y, ZHAO C X, et al Printed Allsolid Flexible Microsurpercapacitors:towards the General Route for High Energu Storage Devices[R]. Nanotechnology, 2014,25(9):094010
[23]ELKADY M F, KANER R B Scalable Fabrication of Highpower Graphene Microsurpercapacitors for Flexible and Onchip Energy Storage[R].Nature Communications, 2013,4(2):1475
[24]WU Z S, PARVEZ K, FENG X, et al Graphenebased Inplane Microsupercapacitors with High Power and Energy Densities[R]. Nature Communications, 2013,4(9):2487
[25]WU Z S, FENG X, CHENG H M, et al Recent Advances in Graphenebased Planar Microsupercapacitors for Onchip Energy Storage[J]. National Science Review, 2014, 1(2):277
[26]WU ZS, PARVEZ K,FENG X, et al Photolithographic Fabrication of Highperformance Allsolidstate Graphenebased Planar Microsupercapacitors with Different Interdigital Fingers[J]. Journal of Materials Chemistry A, 2014, 2(22):8288
[27]KIDAMBI P R, DUCATI C, DLUBAK B, et al The Parameter Space of Graphene CVD on Polycrystalline Cu[J]. Journal of Physical Chemistry C, 2012, 116(42):22492

相似文献/References:

[1]孙永全,郭建英,陈洪科,等.AMSAA模型可靠性增长预测方法的改进[J].哈尔滨理工大学学报,2010,(05):49.
 SUN Yong-quan,GUO Jian-ying,CHEN Hong-ke,et al.An Improved Reliability Growth Prediction Algorithm Based on AMSAA Model[J].哈尔滨理工大学学报,2010,(01):49.
[2]滕志军,李晓霞,郑权龙,等.矿井巷道的MIMO信道几何模型及其信道容量分析[J].哈尔滨理工大学学报,2012,(02):14.
 TENG Zhi-jun,LI Xiao-xia,ZHENG Quan-long.Geometric Model for Mine MIMO Channels and Its Capacity Analysis[J].哈尔滨理工大学学报,2012,(01):14.
[3]李艳苹,张礼勇.新训练序列下的改进OFDM符号定时算法[J].哈尔滨理工大学学报,2012,(02):19.
 LI Yan-ping,ZHANG Li-yong.An Improved Algorithm of OFDM Symbol Timing Based on A New Training Sequence[J].哈尔滨理工大学学报,2012,(01):19.
[4]赵彦玲,车春雨,铉佳平,等.钢球全表面螺旋线展开机构运动特性分析[J].哈尔滨理工大学学报,2013,(01):37.
 ZHAO Yan-ling,CHE Chun-yu,XUAN Jia-ping,et al.[J].哈尔滨理工大学学报,2013,(01):37.
[5]李冬梅,卢旸,刘伟华,等.一类具有连续接种的自治SEIR传染病模型[J].哈尔滨理工大学学报,2013,(01):73.
 LI Dong-mei,LU Yang,LIU Wei-hua.[J].哈尔滨理工大学学报,2013,(01):73.
[6]华秀英,刘文德.奇Hamiltonian李超代数偶部的非负Z-齐次导子空间[J].哈尔滨理工大学学报,2013,(01):76.
 HUA Xiu-ying,LIU Wen-de.[J].哈尔滨理工大学学报,2013,(01):76.
[7]桂存兵,刘洋,何业军,等.基于LCC谐振电路阻抗匹配的光伏发电最大功率点跟踪[J].哈尔滨理工大学学报,2013,(01):90.
 GUI Cun-bing,LIU Yong,HE Ye-jun.[J].哈尔滨理工大学学报,2013,(01):90.
[8]翁凌,闫利文,夏乾善,等.PI/TiC@Al2O3复合薄膜的制备及其电性能研究[J].哈尔滨理工大学学报,2013,(02):25.
 WENG Ling,YAN Li-wen,XIA Qian-shan.[J].哈尔滨理工大学学报,2013,(01):25.
[9]姜彬,林爱琴,王松涛,等.高速铣刀安全性设计理论与方法[J].哈尔滨理工大学学报,2013,(02):63.
 JIANG Bin,LIN Ai-qin,WANG Song-tao,et al.[J].哈尔滨理工大学学报,2013,(01):63.
[10]李星纬,李晓东,张颖彧,等.EVOH 磺酸锂电池隔膜的制备及微观形貌[J].哈尔滨理工大学学报,2013,(05):18.
 LI Xing- wei,LI Xiao- dong,ZHANG Ying- yu,et al.The Preparation and Microcosmic Morphology oEVOH- SO Li Lithium Ion Battery Septum[J].哈尔滨理工大学学报,2013,(01):18.

备注/Memo

备注/Memo:
 基金项目:黑龙江省自然科学基金(F200831);黑龙江省大学生创新创业训练计划项目(201510214050).
更新日期/Last Update: 2019-03-26